Chemique Adhesives Technical Paper – 1 Part and 2 Part Polyurethane Adhesives

A technical paper is available from UK adhesive manufacturer Chemique Adhesives, that discusses one part and two part polyurethane adhesive systems.

The technical paper provides a background to one part (1K) and two part (2K) polyurethane (PUR) adhesive systems and includes some basic chemistry as well as the advantages and limitations of both
systems.Dr Keith Berry, author of the paper and Technical Service Manager at Chemique Adhesives comments “Due to their unique characteristics, polyurethane adhesives are widely used within the industry as they can be formulated to provide a variety of properties enabling them to adhere to many substrates and this paper examines the chemistry, benefits and limitations of this versatile adhesive system”.

Chemique Adhesives started its operations in the UK in 1985, and ever since it has been a pioneer in the development of industry-leading adhesives and sealants, while also achieving an enviable reputation for providing first class service and support to its growing customer base. The company serves all industry
sectors, from aerospace, automotive, and commercial manufacturing to composites, construction, foam, furniture, marine, and transportation.

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About Chemique Adhesives
Established in 1985, Chemique Adhesives is a UK leading manufacturer of high-performance industrial adhesives and adhesive application equipment. Serving a wide range of industries including aerospace, automotive, commercial manufacturing, composites, construction, foam, furniture, marine and transportation, Chemique Adhesives can offer specialist bonding solutions to a multitude of applications whilst providing
the highest level of service, support and advice. The company’s manufacturing and service procedures comply with ISO 9001 ensuring that all products are always tested and manufactured to the highest standard, providing customers with a quality adhesive that they can rely on time after time.

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Technical Paper Objective
The objective of this technical paper is to provide a background to 1-part (1K) and 2-part (2K) polyurethane adhesive systems. This will include some basic chemistry and advantages and limitations of both systems.

Chemistry Background
Polyurethane based adhesives are very versatile with good performance characteristics and they can be formulated to give a wide range of physical properties such as viscosity and application properties such as pot life. Polyurethane systems used for adhesives can be separated into two main classifications, these are the 1K (1-part) and 2K (2-part)systems with both sharing some similarities, and each has distinct advantages and disadvantages.

All polyurethane adhesives use the same chemical reaction as their base, this being a reaction between an isocyanate and a polyol (Figure 1). For 2K systems the isocyanate and the polyol will be manufactured and supplied as separate components. Mixing of the two components just prior to application to create the chemical reaction and fully cross-link the system will be required, to ensure this happens correctly an accurate ratio of components and sufficient mixing must be guaranteed.
Figure 1. Chemical reaction between isocyanate and polyol to create polyurethane linkage

Alternatively, with 1K systems during manufacture the polyol will be reacted with excess isocyanate such
that the polyol chain is terminated with an isocyanate group (figure

2.) The ratio of isocyanate to polyol will help to determine the chain length of the terminated polyurethane prepolymer. This polyurethane prepolymer becomes the reactive component of the 1K system.

Figure 2. Reaction between di-isocyanate and polyol to create a polyurethane prepolymer
To complete the reaction a 1K system will need to interact with water to fully cross-link. Figure 3 shows the chemical reactions that occur between the isocyanate on the end of prepolymer chains of a 1K system and water that result in a polyurea linkage. This means that water needs to be present for a 1K system to crosslink and this can be from moisture in the atmosphere, however, for some adhesives this will be from the application of a water mist prior to the addition of the second substrate being bonded. Alternatively, the prepolymer may be dissolved in a solvent carrier and the prepolymer will react with moisture as the solvent evaporates.

Figure 3. Reaction between isocyanate and water that show the polyurea linkage formed when a 1K system reacts with water

Advantages and Limitations
Polyurethane adhesives of both classifications (1K and 2K) share some advantages and limitations.

Advantages of polyurethane based adhesives include:

• The cure time and pot life can be varied through formulation changes
• Good flexibility can be achieved in the cured product
• Good resistance to solvents when cured
• Excellent adhesion to a wide range of substrates
• Depending on the formulation polyurethane adhesives have a moderate cost
• Can be applied using multiple methods – roller, brush, spray and these can be automatic or manual
• Polyurethane adhesives are non-flammable
• Although they can be solvented, they can also be supplied solvent free
• Heat is not required for cure but can be used to speed up the cure once both substrates are present
• Can stay bonded through a wide range of operating temperatures

Limitations of polyurethane based adhesives include:

• Uncured material is sensitive to moisture
• Although they adhere to most substrates some substrates may require a primer for the polyurethane based adhesive to adhere
• May have short shelf life, generally shelf life is 3-12 months for both 1K and 2K adhesives
• Due to the formation of carbon dioxide which can cause foaming, assemblies made using polyurethane adhesives may need to be held in a press under sufficient pressure whilst the adhesive cures to stop this occurring

Due to the way in which the adhesive is supplied and the formation of urea linkages when curing, 1K adhesives will have some additional advantages:

• No mixing is required
• Easy to apply
• Excellent chemical resistance
• Can be either solvented or solvent free depending on the application required

They will also have some additional limitations:
• Cure time and pot life will be very dependent on the ambient conditions
• Due to the moisture cured nature of the material, once the container is open it will start to react with moisture in the air shortening its shelf life and increasing its viscosity
• Requires sufficient moisture to fully cure, this may mean appropriate level of water misting before application of the second substrate

As there are additional advantages and limitations of 1K polyurethane adhesives, this also applies with 2K
adhesives and the advantages of 2K adhesives include:
• Generally longer shelf lives than 1K polyurethane adhesives
• Cure time more dependent on formulation rather than ambient conditions
• No additional processes (e.g. water-misting) required after application of adhesive

Limitations of 2K polyurethane based adhesives include:

• Correct ratio of components is required to properly cure the adhesive
• Sufficient mixing of the two components before application is required

The issues that most often arise with polyurethane adhesives are usually due to one of the following reasons:
• Using an adhesive with a pot life that is too short for the conditions, such that the substrates are not assembled and under pressure within the pot life
• Insufficient adhesive applied to substrate so there is not enough coverage to give a complete bond.
If one of the substrates is porous this must be taken into account, as should the uniformity of the surface.
• For 1K systems if water misting is required, there is not enough water misting to allow the reaction
to fully take place. This is suggested to be 7-10% of the adhesive applied.
• Not enough pressure within the press. Total surface area of substrate needs to be considered, such that the pressure is approximately 10psi.

Polyurethane based adhesives can be formulated to give a wide range of properties that enable them to adhere to many substrates. There are many advantages to using them as well as a few limitations which must also be considered.

Report Written By: Dr. Keith Berry
Approved By: John Bellerby
Date of Issue: July 2020
Chemique Adhesives and Sealants Limited, Empire Close, Aldridge, West Midlands, WS9 8UR, UK
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